Đặt \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Mg}=y\left(mol\right)\end{matrix}\right.\Rightarrow65x+24y=8,9\left(1\right)\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ \Rightarrow x+y=0,2\left(2\right)\\ \left(1\right)\left(2\right)\Rightarrow\left\{{}\begin{matrix}65x+24y=8,9\\x+y=0,2\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\left(mol\right)\\y=0,1\left(mol\right)\end{matrix}\right.\\ \Rightarrow\%_{Zn}=\dfrac{0,1\cdot65}{8,9}\cdot100\%\approx73\%\\ \Rightarrow\%_{Mg}=100\%-73\%=27\%\)

\(n_{HCl}=2x+2y=0,4\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,4\cdot36,5=14,6\left(g\right)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{14,6\cdot100\%}{14,6\%}=100\left(g\right)\)

\(n_{H_2}=\dfrac{4,368}{22,4}=0,195mol\)

\(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Mg}=y\left(mol\right)\end{matrix}\right.\Rightarrow27x+24y=3,87\left(1\right)\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(\Rightarrow1,5x+y=0,195\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,09\\y=0,06\end{matrix}\right.\)

\(m_{Al}=0,09\cdot27=2,43g\)

\(m_{Mg}=0,06\cdot24=1,44g\)

\(n_{Zn} = a(mol) ; n_{Al} = b(mol) ; n_{Mg} = c(mol)\\ \Rightarrow 65a + 27b + 24c = 44,1(1)\\ Zn + 2HCl \to ZnCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3 H_2\\ Mg + 2HCl \to MgCl_2 + H_2\\ n_{H_2} = a + 1,5b + c = \dfrac{31,36}{22,4} = 1,4(2)\\ Mà : 2a = 3b(3)\\ (1)(2)(3) \Rightarrow a = 0,3 ; b = 0,2 ; c = 0,8\\ \%m_{Zn} = \dfrac{0,3.65}{44,1}.100\% = 44,22\%\\ \%m_{Al} = \dfrac{0,2.27}{44,1}.100\% = 12,24\%\)

\(\%m_{Mg} = 100\% -44,22\% -12,24\% = 43,54\%\)

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\)

\(BTe:\) \(2n_{Fe}+2n_{Zn}=2n_{H_2}\)

\(BTKL:\) \(56n_{Fe}+65n_{Zn}=18,6\)

\(\Rightarrow\left\{{}\begin{matrix}Fe:0,1mol\\Zn:0,2mol\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,1\cdot56=5,6g\\m_{Zn}=65\cdot0,2=13g\end{matrix}\right.\)

nH2 = 13,44/22,4 = 0,6 (mol)

PTHH: Mg + 2HCl -> MgCl2 + H2

nHCl = 0,6 . 2 = 1,2 (mol)

mHCl = 1,2 . 36,5 = 43,8 (g)

nMg = 0,6 (mol)

mMg = 0,6 . 24 = 14,4 (g)

Không thấy mhh để tính%

nH2 = 13,44/22,4 = 0,6 (mol)

PTHH: Mg + 2HCl -> MgCl2 + H2

Cu không tác dụng với HCl bạn nhé

nMg = 0,6 (mol)

mMg = 0,6 . 24 = 14,4 (g)

%mMg = 14,4/20 = 72%

%mCu = 100% - 72% = 28%

nHCl = 0,6 . 2 = 1,2 (mol)

mHCl = 1,2 . 36,5 = 43,8 (g)

\(n_{HCl}=\dfrac{200.14,6\%}{36,5}=0,8\left(mol\right)\\ Đặt:\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Mg}=y\left(mol\right)\end{matrix}\right.\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Tacó:\left\{{}\begin{matrix}65x+24y=12,5\\x+y=0,35\left(mol\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,25\end{matrix}\right.\\ \Rightarrow m_{Zn}=6,5\left(g\right);m_{Mg}=6\left(g\right)\\ b.Tacó:BTNT\left(H\right):n_{HCl}.1>n_{H_2}.2\\ \Rightarrow HCldưsauphảnứng\\ Dungdịchsauphảnứnggồm:\left\{{}\begin{matrix}ZnCl_2:0,1\left(mol\right)\\MgCl_2:0,25\left(mol\right)\\HCl_{dư}:0,8-0,7=0,1\left(mol\right)\end{matrix}\right.\\ m_{ddsaupu}=200+12,5-0,35.2=212,8\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,1.136}{212,8}.100=6,39\%;C\%_{MgCl_2}=\dfrac{0,25.95}{212,8}.100=11,16\%;C\%_{HCl\left(dư\right)}=\dfrac{0,1.36,5}{212,8}.100=1,72\%\)

a) Gọi số mol Zn, Fe là a, b (mol)

=> 65a + 56b = 8,56 (1)

\(n_{H_2}=\dfrac{3,136}{22,4}=0,14\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

           a--->2a-------->a----->a

            Fe + 2HCl --> FeCl₂ + H₂

           b----->2b------->b------>b

=> a + b = 0,14 (2)

(1)(2) => a = 0,08; b = 0,06 

=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,08.65}{8,56}.100\%=60,748\%\\\%m_{Fe}=\dfrac{0,06.56}{8,56}.100\%=39,252\%\end{matrix}\right.\)

b) 

n_KOH = 0,2.0,1 = 0,02 (mol)

PTHH: KOH + HCl --> KCl + H₂O

           0,02-->0,02

=> n_HCl = 0,02 + 2a + 2b = 0,3 (mol)

=> \(C_{M\left(HCl\right)}=xM=\dfrac{0,3}{0,15}=2M\)

c) m = 0,08.136 + 0,06.127 = 18,5(g)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\) (1)

\(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\) (2)

Đặt \(n_{Fe}=a\left(mol\right);n_{Zn}=b\left(mol\right)\)

\(\Rightarrow56a+65b=12,1\)

Từ (1);(2)\(\Rightarrow\Sigma_{n_{H_2}}=a+b=\dfrac{4,48}{22,4}=0,2\)

Ta có hệ: \(\left\{{}\begin{matrix}56a+65b=12,1\\a+b=0,2\end{matrix}\right.\)\(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\%m_{Fe}=\dfrac{0,1.56}{12,1}.100\%=46,28\%\)

\(\%m_{Zn}=\dfrac{0,1.65}{12,1}.100\%=53,72\%\)

b) Từ (1) và (2) \(\Rightarrow\Sigma n_{H_2SO_4}=a+b=0,2\left(mol\right)\)

\(C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,5}=0,4\left(M\right)\).